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Back To Fuel Additives> Manufacturers Common Position Statement

Fatty Acid Methyl Ester Fuels
As a Replacement or Extender for Diesel Fuels
Diesel Fuel Injection Equipment Manufacturers
Common Position Statement 2007

Please note that this statement supersedes all previous joint statements

Background:

Diesel fuel injection equipment (FIE) manufacturers fully support the development of alternative sources of fuel for compression ignition engines. In Europe and in the United States of America, as well as in other countries, fuel resources such as rapeseed methyl ester (RME) and soybean methyl ester (SME), collectively known as fatty acid methyl esters (FAME), are being used as alternatives and extenders for mineral oil derived fuels. Furthermore, the EU Biofuels Directive 2003/30/EC requires member states to ensure that a minimum proportion of biofuels or other renewable fuels are placed on the market.

 

The FIE manufacturers are aware of issues particular to FAME fuels, and have been active in the generation of standards for these fuels. At the time of the first common position statement in 2000 there existed national standards for vegetable oil methyl esters (VOME) in Austria, Italy, Germany and France. The European FAME standard EN14214 was ratified in 2003 and supersedes these national standards.

EN14214 provides the minimum requirements for FAME quality whether used as pure FAME or as a blend component. FAME may be currently blended in quantities of up to 5% in European diesel fuel according to the EN590 specification. In order to reduce the risk of premature failure of the fuel system FAME must conform to EN 14214.  Increasing biodiesel production capacities in the EU have enabled legislative authorities to consider increasing the maximum biodiesel blending level from 5 to 10 percent. Activities are ongoing to standardize and validate biodiesel blends with up to 10 percent biodiesel (B10) in the EU. The FIE industry considers it as essential to maintain the fuel stability level of EU-B5 (IP 20h acc. to modified EN14112) also for future B10 blends. In any case an approval of B10 requires positive validation of B10 specific issues additionally.

 

To date, experience in Europe has been mainly associated with the methyl esters of rapeseed oil. Whether or not the service experience with these fuels will apply/extend to all FAMES (like those derived from soybean, tallow and used frying oil) has yet to be determined.

 

FIE Manufacturers Concerns:

FAMEs are derived from a wide range of base stocks, resulting in a similarly wide range of finished fuel characteristics.

 

Amongst the concerns of the FIE manufacturers are the following fuel characteristics:

  • free methanol - water
  • free glycerine
  • mono, di- and triglycerides
  • free fatty acids
  • total solid Impurity level
  • alkali/alkaline earth metals
  • oxidation stability

 

All FAMES are less stable than mineral oil derived fuels. FAMEs are readily "bio-degradable" in the event of accidental spillage or leakage, which is claimed to be a marketing advantage. On the other hand, the reduced thermal oxidative stability is of major concern to the FIE manufacturers, as the products of fuel ageing can be potentially harmful to the fuel system.

Tests have shown that fuel deterioration can take place in the fuel supply chain and in the vehicle fuel system. Fuel ageing is accelerated in the presence of heat, oxygen, water, metal ions and other impurities. The products of oxidative ageing have been shown to be, corrosive (e.g. organic acids like formic and acetic acids and acids of higher molecular weight). Polymerisation products are also formed and can drop out.

 

A detailed list of potential problems for FIE systems from FAME is presented below.

 

Blends with FAME:

A particular concern is the oxidation stability of FAME blends with sulphur-free diesel fuel (S <10 ppm), which is already available in some parts of Europe and will become more widely used step by step. The oxidation stability of blends as B5 can greatly decrease when using sulphur-free diesel or 15 ppm sulphur diesel such as introduced in U.S.A. in June 2006.

 

In some countries, introduction of unesterified biogenic fuel is examined as a blending component. FIE manufacturers do not agree to this.

 

The FIE manufacturers request their customers to support their efforts to obtain good oxidation stability for biodiesel blends worldwide.

 


 

Diesel Fuel Injection Equipment Manufacturers
Common Position Statement on Fatty Acid Methyl Ester (FAME)

Fuels as a Replacement or Extender for Diesel Fuels

January 2007

 

The FIE manufacturers position:

FIE manufacturers encourage the development of renewable compression ignition fuels. Experience to date with Rapeseed Methyl Ester fuels in Europe suggests that RME conforming to the European standard EN14214 at the point of sale used in mixtures of up to 5% by volume with mineral diesel fuel complying with the EN590 diesel fuel standard should not give end-users any serious problems. The currently agreed position of all FIE manufacturers undersigned is to limit release of injection equipment for admixtures up to a maximum of 5% FAME (meeting the EN14214 standard) with unadulterated diesel fuel (meeting the EN590 standard). The final product B5 must also comply with EN 590. Any new biodiesel blend, e.g. B 10 in Europe or B 20 in the USA has to be standardized (with special emphasis on oxidation, stability) and validated carefully before release,

 

The required quality of the FAME fuel is defined in European standard EN14214, which covers relevant impurities and tramp chemicals from the processing, Suppliers of FAME fuels must be able to demonstrate compliance to this standard at the filling station. There are several risks associated with possible supply chains.

 

For the FIE manufacturers a key property of any FAME fuel is the resistance to oxidation. Aged or poor quality FAME contains organic acids like formic and acetic acids and acids of higher molecular weight as well as polymerization products which attack many components, drastically reducing the service life of the FIE. A list of issues which have been witnessed in service is detailed in the attachment to this document.

 

To date the ASTM specification for FAME fuel (D6751) does not contain a requirement for oxidation stability. A proposal to adopt the EN 14112 Ranchman method with an appropriate limit value for the biodiesel B100 used for blending up to B20 is not yet approved. The FIE manufacturers propose to include an appropriate oxidation stability value in any blend specification (and also ASTM D975 in case it permits blending). The FIE manufacturers are furthermore concerned with the lack of sufficient safeguards against blend quantity.

 

The FIE manufacturers can accept no legal liability for failure attributable to operating their products with fuels for which the products were not designed, and no warranties or representations are made as to the possible effects of running these products with such fuels.

 

Non-compliance of the fuel to standards agreed by the FIE manufacturers, whether being evident by appearance of the known degradation products of these fuels, or their known effects within the fuel injection equipment, (see attached list of known issues) will render the FIE Manufacturers' guarantee null & void,

 

 

 


 

 


Fuel Injection Equipment — Potential Problems with FAME,

(Non-exhaustive list)

Fuel Characteristic

Effect

Failure Mode

Fatty acid methyl esters (general)

Softening, swelling or hardening and cracking of some elastomers Including nitrile rubbers (physical effect depends upon elastomer composition)

 

Displacement of deposits from diesel operation

Fuel leakage

 

 

 

Filter plugging

Free methanol in. FAME

Corrosion of aluminum & zinc

Low flash point

Corrosion of FIE

FAME process chemicals

Entry of potassium & sodium end water hardness (alkaline earth metals)

Entry of free fatty acids hastens the corrosion of nonferrous metals, e.g. zinc

Salt formation with organic acids (soaps)

 

Sedimentation

Filter plugging

 

Corrosion of FIE

 

Filter plugging

 

Sticking moving parts

Free water

Reversion (Hydrolysis) of FAME to fatty acid and methanol

Corrosion

Sustainment of bacterial growth

increase of electrical conductivity of the fuel

 

 

Corrosion of FIE

Filter plugging

Free glycerine

Corrosion of non-ferrous metals

Soaking of cellulose filter

Sediment on moving parte and lacquering

 

Filter plugging
Injector caking

Mono-, dl- and tri-glycerine

Similar to glycerine

Injector caking

Higher modulus of elasticity

Increase of injection- pressure

Potential for reduced service life

High viscosity at low temperature

Generation of excessive heat locally in rotary type distributor pumps

Higher stressing of components

Fuel delivery-problems

Pump seizures

Early life failures

Poor nozzle spray atomization

Solid impurities / particles

Potential lubricity problem

Reduced service life Nozzle seat wear Blocked nozzles

Ageing products

 

 

Corrosive acids (formic & acetic)

Corrosion of all metal parts

May form simple cell

Corrosion of FIE

Higher molecular organic acids

Similar to fatty acid

 

Polymerisation products

Deposits, precipitation especially from fuel mixes

Filter plugging

Lacquer formation by soluble polymers in hot areas

 

 

 

Fatty Acid Methyl Ester Fuels — Joint FIE Manufacturers Statement, issued January 2007

 

 

 

 


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